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陈林海. 基于同时蒸馏萃取-气质联用法(SDE-GC-MS)分析不同品种原料坦洋工夫红茶的香气组分[J]. 茶叶学报,2023,64(6):51−63. DOI: 10.20045/j.cnki.issn.2096-0220.2023.06.005
引用本文: 陈林海. 基于同时蒸馏萃取-气质联用法(SDE-GC-MS)分析不同品种原料坦洋工夫红茶的香气组分[J]. 茶叶学报,2023,64(6):51−63. DOI: 10.20045/j.cnki.issn.2096-0220.2023.06.005
CHEN Lin-hai. Aromatics in Tanyang Gongfu Black Teas of Different Tea Varieties Analyzed by SDE-GC-MS Method[J]. ACTA TEA SINICA, 2023, 64(6): 51-63. DOI: 10.20045/j.cnki.issn.2096-0220.2023.06.005
Citation: CHEN Lin-hai. Aromatics in Tanyang Gongfu Black Teas of Different Tea Varieties Analyzed by SDE-GC-MS Method[J]. ACTA TEA SINICA, 2023, 64(6): 51-63. DOI: 10.20045/j.cnki.issn.2096-0220.2023.06.005

基于同时蒸馏萃取-气质联用法(SDE-GC-MS)分析不同品种原料坦洋工夫红茶的香气组分

Aromatics in Tanyang Gongfu Black Teas of Different Tea Varieties Analyzed by SDE-GC-MS Method

  • 摘要:
    目的 分析不同品种原料制作的传统型坦洋工夫红茶香气组分,为了解品种与香气间的相关性、提升红茶加工工艺提供参考。
    方法 以‘金牡丹’‘茗科1号(金观音)’‘坦洋菜茶’‘福安大白茶’‘梅占’等不同品种一芽二、三叶鲜叶为原料,按照传统型坦洋工夫红茶初制工艺加工红茶,采用同时蒸馏萃取法(SDE)结合气相色谱-质谱联用法(GC-MS)检测其香气组分,分析不同红茶样的香气组成,并进行感官审评与相关性分析等。
    结果 经SDE-GC-MS检测,5个红茶样中各类香气组分共计109种,其中金牡丹香气组分最多,高达52种;香气种类含量最高的是醇类,其次为酯类、醛类等;金观音中香叶醇相对含量为最高,达48.13%;梅占中芳樟醇及壬醛相对含量均最高,分别为22.97%、12.82%;坦洋菜茶中松油醇相对含量最高,为1.78%;3,7-二甲基-1,5,7-辛烯-3-醇在福安大白茶相对含量最高,为11.66%;参试品种均含有香叶醇或其异构体、芳樟醇等重要的香气成分。感官审评结果表明,参试品种均呈现良好的香气,其中金牡丹香气和滋味中花果香最明显,感官审评得分最高;聚类分析表明,金牡丹与坦洋菜茶、梅占与福安大白茶香气成分最为相似;相关性分析表明,香气、滋味得分与香气组分含量具有一定相关性。
    结论 5个茶树品种均适制优质坦洋工夫红茶,其香气组分含量与茶树品种、加工工艺有一定关联性。品种间香气组分含量及比例的差异性,是造成不同品种原料坦洋工夫红茶香气呈现不同特征的重要原因。

     

    Abstract:
    Objective Aromatics of traditional Tanyang Gongfu black teas made from the leaves of different varieties of tea cultivars were analyzed.
    Method One bud and two or three leaves of 'Jin Mudan', 'Mingke No. 1'(Jin Guanyin), 'Tanyang Caicha', 'Fu'an Dabaicha', and 'Meizhan' teas were used for the study. Following the primary traditional Tanyang Gongfu black tea process, the prototype products were made and subjected to the simultaneous distillation extraction (SDE) and followed by a chemical analysis using the gas chromatography-mass spectrometry (GC-MS). The analytical results were correlated with the sensory evaluation scores on the brewed teas.
    Result One-hundred-and-nine volatile compounds were identified in the 5 black tea samples. Among them, Jin Mudan tea had the most, up to 52, different substances. Quantitatively, alcohols were the most and followed by esters, aldehydes, and others. The highest relative content of geraniol at 48.13% was found in Jin Guanyin tea; those of linalool at 22.97% and nonanal at 12.82% in Meizhan; that of terpineol at 1.78% in Tanyang caicha; and that of 3,7-dimethyl-1,5,7-octen-3-ol at 11.66% in Fu'an Dabaicha. All varieties of the teas contained geraniol or its isomers, linalool, and other major aromatics. All brewed teas were fragrant, however, the floral and fruity notes of Jin Mudan tea stood out among them. The cluster analysis on the aromatic compositions indicated a close similarity between Jin Mudan and Tanyang Caicha, as well as between Meizhan and Fu’an Dabaicha. The sensory score was found significantly correlated with the volatile components in the teas.
    Conclusion The 5 varieties of tea cultivars were all adequate for producing a high-quality Tanyang Gongfu black tea. However, the sensory panel’s perceptions on the teas varied due to the chemical differentiations of the leaves with which they were processed. Both content and proportion of the aromatics in the tea leaf significantly altered the characteristics of a tea product made from the leaves.

     

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